ࡱ> TV  !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSXYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~Root EntrydO)dUPowerPoint Document(ASummaryInformation(W|dDocumentSummaryInformation8\( / 0DTimes New Romant0v 00( 0D[SOes New Romant0v 00( 0  DWingdingsRomant0v 00( 0 0DўSOgdingsRomant0v 00( 0 @DWingdings 3mant0v 00( 0 PDeckYSOings 3mant0v 00( 0  ` .  @n?" dd@  @@`` H @ c 1?@87uʚ;2Nʚ;g4CdCdv 0$ppp@ <4!d!d` 0`<4dddd` 0` ? %(,{]NzMMOs^a  1 0MMOSTir [Ag(NH3)2]+ 0 [Cu(NH3)4]2+ 0 [Fe(CN)6]3 0 [Pt (C2H4)Cl2]2   < # + # + # +  # + # + # +  # + # +  # + # + # + # + #  ; \~b-N_ё^\yP[NQ*NMSORP[byP[b_bvMyP[b~yP[ ё^\NMSOKNv~T^8^3z[0 / /# . [Ag(NH3)2]+ D Ag + 2 NH3 ُS^v z^^8^\ s^a8^peKi_\ vS Ag + 2 NH3 D [Ag(NH3)2]+ S^s^a8^peKf _'YKf1/Ki Kf 1\S3z[8^pe Ki N3z8^pe _NSy8^pe 4 J  # # + # + # + # + # + #    1 1.0dm3 0.10moldm-3CuSO4nm-NReQ6.0moldm-3vNH3H2O 1.0dm3 ,Bls^aenm-NCu2 vSm^0( K3zCu(NH3)42 =2.091013 ) h     z   ]w: (W25!e, HCN v Ka= 4.9310-10 [Zn(CN)4 ]2 v K3z = 1.01016 BlS^: [Zn(CN)4]2 + 4H+  Zn2+ + 4HCN v K 0 >.   l  ` (W1.0dm3 nm-N+T1.0molAgNO3 N 2.0molNH3H2O, {nm-NT~R(Ag , NH3, Ag(NH3)2 )vSm^0S_ReQzHNO3OAg(NH3)2 Sm^M:N1.010-2moldm-3e,nmvpH:NUO?" dd@,t? vKd@  @` n?" dd@   @@``PR    @ ` ` p>> > > =(     N gֳgֳ ?"0U2  LUSQdkYkHrh7h_  "  Hgֳgֳ ?"5U9b  8USQdkYkHre,g7h_ ,{N~ ,{ N~ ,{V~ ,{N~     BCDEF@?""C>>(( B](3"@>BI[p])^ Z.]]{^ PCEH@"" 2  Ztd @?"'Y <  ("  S BCDE0F83?LL+&<*O&b*p6?733-2 9<73R3z6B?<PTc y+BYivvyueXD:.4=<L8^?q9?E5397& !#'#<HX j |& z63bX! "+&@"    BCDEtF|fd@?]]z}&}}/Kw+}}|yrj`"! r!f]OA72&'!!&!7/'"p&O,2%'+9Q]ovz|z],ztL94/o*L!+*# !%z,f#R(9+)( &/Jb vz@"@ b  S ,BCDEPFX?TTS0--220a2A3(13$.C.@Q>g?z@A@D@U?@@\i.TyjR&H;CmJDEC/F^CHE8"%7;X:(86:u8S><7/5$.) )1HWebpvj|Il-n"\]bVM>,+t7S0@"_    zBMCDEhFp2 @?3/LA=BWIn=93*  $,(l+U(D$2358@" H   S BCDEF?|!/8BKU]lu~z !(18CK|jx~ye[Sb{wn t /5BJV`ZVNEJzCj1g6[BQ#R1KK@>>G A8/5C2X*{%)7?9<HXls0<Nbo~~|'2<KX_hox~pd_]_[ted`V]K]/` b_c_]][`_]`~`l[]aQ]Fc:`,]$XE4(iO0-?W_xc`eHa5aa`cam]=_ _` eq@"    S LB9CDE`Fh?  ">Vl  -83(+ ^@"  14@"P TZ (a  # "a(T    $BtC DE@FHd @?.0HY hp.sEs Q  R7 !$@(al   C BtCsDE0F83?LLK#i'#'2: 31/h/)/57/J/2=:)/#L)p8>418/#6Qp   $)Q)w!,74:45:P@o1053#!2!V k #-MfssrY}\R  8 K#@( L    BtCvDE<FDfd@?OOr.tBu0uHsYqhjpbsZs `VMF =1 v]LE#1#l3N,5$ #)"s&WD/)e0)$*$'0b-!*0,|'?'s!]B")!%c(G%#,E[nr@(3   C ^BRCDElFt?[[Jszb 7"<e2z>Df!!8~&'$#s "5UE z.,:3C@JWQuQ7Q'MH*@%zW oEb98k8"#5J@4h   C VBPC>DEF?zz '/1(/;/[.n//001/.-G12122/2>131/.%0C1e02//,E/--/6+a,r/0/031F0S0d.01/1/1 -1/C/-/-,+8(A"HO O'O-L1F6;:=:<><$;=;=u<\9 <8<f:8<:::9;99n;R<3<;<;;u=E:=;=;a:9;;;<7;;g::6.'@9[TZ  aY  # "a YT    $BtCDE@FHd @?.0HY hp1sIsQW; !$@ aY}   C BtC{DE0F83?LLK&i*&*5? 612h2,29;2J26A?,/&L,p<B84<2&6Qp $,Q,w#/;8?85?PEo4396&!#2#Vk  &- Mfssz_}cX  !8"K&@ YL    BtC}DE<FDfd@?OOx.{B|0|HzYxhqphs_s`VMF"=!1!v]LE%1!!%!l6N.5&"%,$s(W!D/+!e3)&-&*3b0!-3.|*?!*s#]B!$,#'c+G'%.I`tx@ @Y   C ^BQCDElFt?[[Nzh :$<e2z>Df!##7}!()$%s" !$4U ! 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(6 c '+?4\GvYRxAZE9-g)6+ 14@" & eTZ U>  # "U>T    $BCDE@FHd @?%*JnBY/ !$@]>/   C BCDE0F83?LL=9U?p9?Q_RL%LECbL{VYLLR+cP_uC9CZdU%O8ZHLY9m'"'0,/CSCr5GYT_U _#h<OMM`VrR9255  80Qi}90+ ,2.3=9@U6UL    BCDE<FDfd@?OO%631/#qY C14%&#(811+8t$V19R"F :38B7o<X1I&7$+A-2Nb:=D$:?NIDkN3F?1?q#I$-5'/17B5t;PA:;8Fo @U6  C ^BCDElFt?[[wX 7,0$R''-'4*_(-, ' .V',3-525n-3=?/9o4~136 .'1P3s,'04'T333GRhX?. F 0E  X+    G -  [ _W- 8Vw@_$  C VBCdDEF?zz2#? LP!M0LJKZLgLNOPLKJ P7RPO_RRMQP S!PNLlKNPNQM2MRGzMIIL>GaGoM~OLO PO'O4KPN]PfMrPLPJMM*JgMIFA8*?IPX_tcF_/aaac`cBa-]a\ae^@a+^__\a\]_akaGa-a__c^~c[_3c__aa_aFa_aT^_XL?2@b'TZ ]> # "]>T   $BCDE@FHd @?%,MsB]1 !$@]>I  C BCDE0F83?LL=;UAp;ASaUN%NEEbN{X\NNT+fPauE;E]fW%Q8]HNY;m(#( 1-/ESEr7I\VaW a#k<QMO`XrU;377  81Qi};1, .3.5=;@]>gL   BCDE<FDfd@?OO%6542%qY"C44'&%*;44-;t%V49V"I =5;E:o?X4I(7%-D/5Rb==G$=BRLGkR3IB4Bq%I%-7)249E7t>PD:>;It @]>  C ^BCDElFt?[[{\ 9.0&R((.(4,_*.. ( 0V(.5.727n.5?A/;o6~358 0'3P5s.(25(T555JUk\A/ F 0E  X+   G -  [ _W- :Y{@g,  C VBCgDEF?zz4$A NS!P0NJMZNgNPQRNML R7UPR_UUPSS U!RNNlMPSPSO2ORJzPKKN>IaJoP~QNQ RQ'Q4MPP]RfPrSNRLPP*LgPKHC:+AKR[btfFb/dddfcfBd-`d_dea@d+abb_d_`bdkdGd-dbbfa~f[b3fbbdd_dFdbdTabZNA4@j,/  # l]1 ?"p  LUSQdkYkHrh7h_      f_1 ?" `    NUSQdkYkHroRh7h_    fc1 ?"``  Z*   fDh1 ?"`   \*   fl1 ?"`   \*Z  Bk#޽h? ? f̙33p   0(  x  c $º 0U2   x  c $ú 5Ub  x  c $hĺ    H  0޽h ? ̙33j  P(  r  S w  m  H  0޽h ? f̙33  F>`(    S ~|gֳgֳ ? <$ 0    Hgֳgֳ ?`P,$D 0  20]w: Zn(NH3)42 T Zn(OH)42 vy8^peR+R:N K1 = 1.010-9 T K2 = 3.3310-16 , Kb NH3H2O = 1.810-5 . ՋBl: (1) S^ Zn(NH3)42 + 4OH  Zn(OH)42 + 4NH3 v K- $,,66R@- $66@@QA- $@@JJOC- $JJTTNE- $TT^^LG- $^^hhJH- $hhrrHJ- $rr||GL- $||EM- $CO- $AP- $?R- $=S- $;T- $9U- $7W- $5X- $3Y- $1Z- $/[- $-\- $+]- $) ^- $' ^- $&&% _- $&&00# `- $00::! `- $::DD a- $DDNN b- $NNXXb- $XXbbc- $bbllc- $llvvc- $vvd- $d- $d- $ e- $ e- $ e- $e- $f- $---&&&yJK&--&&- $yKyK;- $KK\- $KK}- $KK- $KK- $KK- $KK- $KK- $KK- $KK- $KK $KK- $KK- $KK- $KK- $KK- $##KKz- $#--K#KX- $-77K-K9- $7AAK7K- $AJJKAK&&&- &H$"{}    BDFHHII@@JJ?@y@yyyz{&&-&& &&-&&H$"{}    BDFHHII@@JJ?@y@yyyz{&&- $yKyK;- $KK\- $KK}- $KK- $KK- $KK- $KK- $KK- $KK- $KK- $KK $KK- $KK- $KK- $KK- $KK- $##KKz- $#--K#KX- $-77K-K9- $7AAK7K- $AJJKAK&- --&&& O&---N ->-5C--(---&&wc~@m3 ~~ ~0- &x/JP-3-$L66668:9887899888::9==@DEEEEGEECDC@>;9899: 9:;8899 6%5'5*5-2/0215582:/=0@6B5E2G2I4IDGNOI@x>x3z4{5~56--&&x5JV&--&&b- $x5J5J?x?M- $x?J?JIxIK%- $xIJIJSxS- $xSJSJVxV&&&- &$]{J}JJJLOQRTUUUSPLJBJDJFIHHHGIEI8G5F6E8D;C;B;@9>8;8996;493908.8,:+<*;';#: <9;>=<; <=;<?CEHIJJKKLLMJIB?>=<;<99;:;;;=;<<<z<x=yByFzI{J&&-&& &&-&&$]{J}JJJLOQRTUUUSPLJBJDJFIHHHGIEI8G5F6E8D;C;B;@9>8;8996;493908.8,:+<*;';#: <9;>=<; <=;<?CEHIJJKKLLMJIB?>=<;<99;:;;;=;<<<z<x=yByFzI{J&&b- $x5J5J?x?M- $x?J?JIxIK%- $xIJIJSxS- $xSJSJVxV&- --&&&z:GS-f-$TBBCCBCCC|C{@z>zB{FEEEEEEFEEEEJLPQRRQOLHFF GF F$F,F4F;FDFFDF@F:DABD=D3D+DCD DEDCB@=>CFIKKMNOLMJJKIGE?>BBDB--&& F&--&&- $  FF $   F F&&&- &8$  $ ) , 0 48;>@BE@=:61,(% &&-&& &&-&&8$  $ ) , 0 48;>@BE@=:61,(% &&- $  FF $   F F&- --&&&zH.--$zz&z-{({#{|}~ #"               "$%&()*,-/245689;=?BDEFG!G'GGGFEC@>;8632-*(%"        ~|{zzz--&&C--4$#'+/37:=@B@=950(#--&&pH&p=&--&&1- $pp}- $pp$$- $$p$p..- $.p.p88- $8p8p==&&&- &$$ dhkmooo<<<  &&-&& &&-&&$$ dhkmooo<<<  &&1- $pp}- $pp$$- $$p$p..- $.p.p88- $8p8p==&- --&&&-pA-3-$L232#3'5+63594C4I3O4T5Y6`4h4t5x7632367556421010///11332465656755 5$5)21252:2@/C.H.M1R/W-[-`2c1i/m/o1o@;<:0 1 222--&&3pH&--&&_- $3p3p==V+- $=p=pGG- $GpGpHH&&&- &$O FFGdGhFkFmEoCoBo5l3j4i6h8f8d8`7]6X5T6O8L7I7E6A6>7=99858/7)9%78<:9 89:998777:88;9:9:;;:;z:q:f8]:R7J7D9A7<86819*:$99:9 9:?B E F&&-&& &&-&&$O FFGdGhFkFmEoCoBo5l3j4i6h8f8d8`7]6X5T6O8L7I7E6A6>7=99858/7)9%78<:9 89:998777:88;9:9:;;:;z:q:f8]:R7J7D9A7<86819*:$99:9 9:?B E F&&_- $3p3p==V+- $=p=pGG- $GpGpHH&- --&&& l,--$[  $ + & "   *1<HPbhtx&+1?HT^bfhij k%kkkjeRM>90)ungbP=3(     --&& :mE-f-$z ? < : < = @ BBBBABB$B'B)B.B3A9A@BIBNBQBYB\B`BiBuByBBABBBBBBABAABAABBBBBBBA B"B$B'B+B2B9A<B?BLAYBcAfAh@j?k>l<l@lAkBjCiC\DRCND>D:D5D1D+DDC DCDCDCCCCDCCDDDDDDDDCDD}DvDoChDbDQDLD=D4DC C C A @ ?--&&&QK&Q@&--&&/- $QQv- $Q$Q$- $Q$$.Q.- $Q..8Q8- $Q88@Q@&&&- &$$VX?^?Q?QQRSV&&-&& &&-&&$$VX?^?Q?QQRSV&&/- $QQv- $Q$Q$- $Q$$.Q.- $Q..8Q8- $Q88@Q@&- --&&&Q.D-3-$L]5b5h5m5q7v9}77767887779965689878753 232111$4(3,646:4=6@8D8J9O8Z9^:c7g7k8n7s5|4441/041..54113C>?Q=Q1S3V4Z4]5--&&Q5K&--&&_- $Q55?Q?_/- $Q??IQI- $QIIKQK&&&- &$OVIXJ\JJJIHGE8568;;:9889;9988:;;;y:s;o9i;c>^=Z<U;O;E==;9<5;19.9':<:; ><=<<>==>=<;<99;::;{;t=n;i<a<]<T;Q=QARESIVI&&-&& &&-&&$OVIXJ\JJJIHGE8568;;:9889;9988:;;;y:s;o9i;c>^=Z<U;O;E==;9<5;19.9':<:; ><=<<>==>=<;<99;::;{;t=n;i<a<]<T;Q=QARESIVI&&_- $Q55?Q?_/- $Q??IQI- $QIIKQK&- --&&&S---$[SS&S,T'T#TUX]dt{ .;?CQ\aiqu|!&{tgME7-$~se\YVTSSS--&&T<H-f-$zTBT?T<U>U@UCVEXEZE]EcDfEiEoEqEtExE}DDEEEEEEEEEEEDEEEEEED ED!D+E2D9D<E?EHEQE\E_EaEdDjEmEoEqEuE}EDEEDEDDCBA?CDEFGGGGGGG{GuGgGcFUGLFBG:G2G.G*G%G!FGFFG GGGGGGGGGGGGGGGGGG~GeGWGTFTETCTB--&&&G& &Gy& --]-- ~@@  ~~ ~0- .2 ھλƽ;;;:;;;.--~-- ~@m3 ~~ ~0- . 2 *1 . .2 V λ+*++*+. . 2 L[ . .2 L.Ag(NH.~@@ $ ~~ ~0- . 2 T3 .~@m3 ~~ ~0- . 2 L) .~@@ & ~~ ~0- . 2 T2 .~@m3 ~~ ~0- . 2 L] .~@@ ( ~~ ~0- . 2 :+ .~@m3 ~~ ~0- . 2 L+. .2 [Cu(NH.~@@ 3 ~~ ~0- . 2 3 .~@m3 ~~ ~0- . 2 ).~@@ 5 ~~ ~0- . 2 4.~@m3 ~~ ~0- . 2 ].~@@ 7 ~~ ~0- . 2 w2+ .~@m3 ~~ ~0- . 2 +. .2 [Fe(CN).~@@ B ~~ ~0- . 2 6.~@m3 ~~ ~0- . 2 ].~@@ D ~~ ~0- . 2 3. . 2 .~@m3 ~~ ~0- . 2 +. .2 [Pt (C.~@@ P ~~ ~0- . 2 2 .~@m3 ~~ ~0- . 2 H.~@@ R ~~ ~0- . 2 4.~@m3 ~~ ~0- . 2 )ClR.~@@ T ~~ ~0- . 2  2.~@m3 ~~ ~0- . 2 ].~@@ V ~~ ~0- . 2 .2 .--N-- ~@m3 ~~ ~0- .+2 ɣĽ뼸+++*++*++*+*. .(2 ӻγɵ+++*++*++**. .(2 ӻӣ+++*++*++**. .(2 ֮ĽϷdzȶ+++*++*++*+.--"System !~-&TNPP & õʾĸģ õƬ _foodmatefoodmateCurrent User 8